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Molina Ontoria, Agustín ; Zimmermann, Iwan ; García Benito, Inés ; Gratia, Paul ; Roldán Carmona, Cristina ; Aghazada, Sadig ; Graetzel, Michael ; Khaja Nazeeruddin, Mohammad ; Martin León, Nazario | Wiley | 2016-05-17New star-shaped benzotrithiophene (BTT)-based hole-transporting materials (HTM) BTT-1, BTT-2 and BTT-3 have been obtained through a facile synthetic route by crosslinking triarylamine-based donor groups with a benzotrithiophene (BTT) core. The B[...]texto impreso
Suarez, Margarita ; Ruiz, Alberto ; Almagro, Luis ; Coro, Julieta ; Maroto, Enrique E. ; Filippone, Salvatore ; Molero, Dolores ; Martínez-Alvarez, Roberto ; Martin León, Nazario | ACS | 2017-04-13The diastereoselective synthesis of cis and trans steroid-fulleropyrrolidines hybrids by reaction of N-metalated azomethine ylides [Cu(II) or Ag(I)] with the appropriate chiral ligand and C60 is described. The experimental findings reveal that t[...]texto impreso
Vidal, Sara ; Izquierdo, Marta ; Alom, Shamim ; García-Borrás, Marc ; Filippone, Salvatore ; Osuna, Silvia ; Solà, Miquel ; Whitby, Richard J. ; Martin León, Nazario | RSC | 2017-10-14The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been [...]texto impreso
[60]Fullerene hybrids have succesfully been used as catalysts in hydrogen transfer reactions, namely ketones reduction and Nalkylation with alcoholes. Due to the poor solubility in polar solvent, these hybrids behave as homogeneous/heterogeneous[...]texto impreso
Leng, Faqiang ; Gerber, Iann C. ; Lecante, Pierre ; Bentaleb, Ahmed ; Muñoz, Antonio ; Illescas Martínez, Beatriz M. ; Martin León, Nazario ; Melinte, Georgian ; Ersen, Ovidiu ; Martínez, Hervé ; Axet, Rosa ; Serp, Philippe | Wiley | 2017-08The C66(COOH)12 hexa-adduct has been successfully used as a building block to construct via carboxylate bridges 3D networks with very homogeneous sub-1.8 nm ruthenium nanoparticles. The obtained nanostructures are active in nitrobenzene selectiv[...]
