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Título:
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Effect of Incarcerated HF on the Exohedral Chemical Reactivity of HF@C60
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Autores:
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Vidal, Sara ;
Izquierdo, Marta ;
Alom, Shamim ;
García-Borrás, Marc ;
Filippone, Salvatore ;
Osuna, Silvia ;
Solà, Miquel ;
Whitby, Richard J. ;
Martin León, Nazario
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Tipo de documento:
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texto impreso
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Editorial:
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RSC, 2017-10-14
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Dimensiones:
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application/pdf
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Nota general:
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info:eu-repo/semantics/openAccess
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Idiomas:
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Palabras clave:
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Estado = Publicado
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Materia = Ciencias: Química: Química orgánica
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Tipo = Artículo
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Resumen:
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The first chemical modification on the brand new endohedral HF@C60 is reported. In particular, the isomerization from optically pure (2S,5S)-cis-pyrrolidino[3,4:1,2][60]fullerene 2b to (2S,5R)-trans-pyrrolidino[3,4:1,2][60]fullerene 2b has been studied and compared with empty C60 (2a) and endohedral H2O@C60 (3). The comparative study shows a kinetic order for the isomerization process of H2O@C60 ? HF@C60 ? C60, thus confirming the effect of the incarcerated species on the zwitterionic intermediate stability.
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En línea:
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https://eprints.ucm.es/id/eprint/46345/1/HF%40C60%20Chem%20Commun-preprint.pdf
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