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Título:
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Pasteur made simple – mechanochemical transformation of racemic amino acid crystals into racemic conglomerate crystals
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Autores:
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Viedma Molero, Cristóbal ;
Lennox, Cameron ;
Cuccia, Louis A. ;
Cintas Moreno, Pedro ;
Ortiz, José E.
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Tipo de documento:
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texto impreso
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Editorial:
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Royal Society of Chemistry, 2020
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Dimensiones:
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application/pdf
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Nota general:
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info:eu-repo/semantics/restrictedAccess
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Idiomas:
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Palabras clave:
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Estado = Publicado
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Materia = Ciencias: Geología: Cristalografía
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Materia = Ciencias: Química: Química orgánica
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Tipo = Artículo
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Resumen:
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Conglomerate crystallization is required for many deracemization or enantioenrichment protocols. Here, we report the metal-mediated mechanochemical transformation of racemic compounds of some proteinogenic amino acids – valine, leucine and isoleucine – into their corresponding conglomerates. Specifically, ZnO has the ability to promote and stabilize the conglomerate phase of these amino acids to an extent where the racemic compound is not observed.
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En línea:
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https://eprints.ucm.es/id/eprint/60572/1/Pasteur%20made%20simple%20%E2%80%93%20mechanochemical%20transformation%20of%20racemic%20amino%20acid%20crystals%20into%20racemic%20conglomerate%20crystals.pdf
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