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Frechero, M. A. ; Rocci, Mirko ; Schmidt, Rainer ; Díaz Guillén, M. R. ; Durá, O. J. ; Rivera Calzada, Alberto Carlos ; Santamaría Sánchez-Barriga, Jacobo ; León Yebra, Carlos | Sociedad Española de Cerámica y Vidrio | 2012-01Here we show impedance spectroscopy measurements on a bicrystal of the ionically conducting yttria stabilized zirconia (YSZ). By using micrometer sized electrodes it is possible to measure ionic transport perpendicular to a single grain boundary[...]texto impreso
Durá, O. J. ; López de la Torre, M. A. ; Vázquez, L. ; Chaboy, J. ; Boada, R. ; Rivera Calzada, Alberto Carlos ; Santamaría Sánchez-Barriga, Jacobo ; León Yebra, Carlos | American Physical Society | 2010-05-01We report on the effect of grain size on the ionic conductivity of yttria-stabilized zirconia samples synthesized by ball milling. Complex impedance measurements, as a function of temperature and frequency are performed on 10 mol % yttria-stabil[...]texto impreso
Frechero, M. A. ; Rocci, Mirko ; Sánchez Santolino, Gabriel ; Salafranca, Juan ; Schmidt, Rainer ; Díaz Guillén, M. R. ; Durá, O. J. ; Rivera Calzada, Alberto Carlos ; Varela del Arco, María ; Santamaría Sánchez-Barriga, Jacobo ; León Yebra, Carlos | Nature Publishing Group | 2015-12-17The blocking of ion transport at interfaces strongly limits the performance of electrochemical nanodevices for energy applications. The barrier is believed to arise from space-charge regions generated by mobile ions by analogy to semiconductor j[...]texto impreso
Durá, O. J. ; Boada, R. ; Rivera Calzada, Alberto Carlos ; León Yebra, Carlos ; Bauer, E. ; López de la Torre, M. A. ; Chaboy, J. | American Physical Society | 2011-11-24This work reports on the effect of grain size on the electrical, thermal, and structural properties of CuAlO_(2) samples obtained by solid-state reaction combined with ball milling. Electrical characterization made in microcrystalline and nanocr[...]texto impreso
Durá, O. J. ; Boada, R. ; López de la Torre, M.A. ; Aquilanti, G. ; Rivera Calzada, Alberto Carlos ; León Yebra, Carlos ; Chaboy, J. | American Physical Society | 2013The local order around Zr and Y atoms of nanocrystalline yttria-stabilized zirconia (YSZ) powders with different grain sizes has been investigated by x-ray absorption spectroscopies. The samples were prepared by means of mechanical alloying with[...]
