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Título:
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Controlling Vilsmeier-Haack processes in meso-methylBODIPYs: A new way to modulate finely photophysical properties in boron dipyrromethenes
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Autores:
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Palao Utiel, Eduardo ;
Montalvillo Jiménez, Laura ;
Esnal Martínez, Ixone ;
Prieto Montero, Ruth ;
Rodríguez Agarrabeitia, Antonia R ;
García Moreno, Inmaculada ;
Bañuelos Prieto, Jorge ;
López Arbeloa, Íñigo María ;
Moya Cerero, Santiago de la ;
Ortíz García, María Josefa
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Tipo de documento:
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texto impreso
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Editorial:
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Elsevier, 2017-06
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Dimensiones:
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application/pdf
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Nota general:
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info:eu-repo/semantics/restrictedAccess
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Idiomas:
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Palabras clave:
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Estado = Publicado
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Materia = Ciencias: Química: Optica
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Materia = Ciencias: Química: Química orgánica
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Tipo = Artículo
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Resumen:
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In the herein work we report the fine and selective control of competitive processes when submitting meso-methylBODIPYs to Vilsmeier-Haack reaction conditions. These competitive processes generate BODIPYs with opposed photophysical properties, from highly fluorescent dyes enabling laser emission, to non-fluorescent singlet-oxygen photosensitizers. The synthetic control is exerted on the basis of the structure of the starting BODIPY, as well as the electrophilic character (hard or soft) of the formylating reagent.
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En línea:
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https://eprints.ucm.es/45051/1/agarrabeitia_controlling%20vilsmeier-Elsevier-2017.pdf
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