Título:
|
Generalized Green-Kubo formulas for fluids with impulsive, dissipative, stochastic, and conservative interactions
|
Autores:
|
Ernst, M. H. ;
Brito, Ricardo
|
Tipo de documento:
|
texto impreso
|
Editorial:
|
American Physical Society, 2005-12
|
Dimensiones:
|
application/pdf
|
Nota general:
|
info:eu-repo/semantics/openAccess
|
Idiomas:
|
|
Palabras clave:
|
Estado = Publicado
,
Materia = Ciencias: Física: Termodinámica
,
Tipo = Artículo
|
Resumen:
|
We present a generalization of the Green-Kubo expressions for thermal transport coefficients mu in complex fluids of the generic form mu=mu(infinity)+integral(infinity)(0) dtV(-1)(0), i.e. a sum of an instantaneous transport coefficient mu(infinity), and a time integral over a time correlation function in a state of thermal equilibrium between a current J and its conjugate current J(epsilon). The streaming operator exp(tL) generates the trajectory of a dynamical variable J(t)=exp(tL)J when used inside the thermal average (0). These formulas are valid for conservative, impulsive (hard spheres), stochastic, and dissipative forces (Langevin fluids), provided the system approaches a thermal equilibrium state. In general mu(infinity)not equal 0 and J(epsilon)not equal J, except for the case of conservative forces, where the equality signs apply. The most important application in the present paper is the hard sphere fluid.
|
En línea:
|
https://eprints.ucm.es/id/eprint/21348/1/Brito08libre.pdf
|