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Título:
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Thermodynamic properties of the fluid, fcc, and bcc phases of monodisperse charge-stabilized colloidal suspensions within the Yukawa model
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Autores:
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Fernández Tejero, Carlos ;
Lutsko, J. F. ;
Colot, J. L. ;
Baus, Marc
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Tipo de documento:
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texto impreso
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Editorial:
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American Physical Society, 1992-09-15
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Dimensiones:
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application/pdf
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Nota general:
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info:eu-repo/semantics/openAccess
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Idiomas:
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Palabras clave:
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Estado = Publicado
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Materia = Ciencias: Física: Termodinámica
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Tipo = Artículo
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Resumen:
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The thermodynamic properties of the Yukawa model for colloidal suspensions are determined theoretically from the Rogers-Young integral equation for the fluid phase and from a recently introduced van der Waals-like theory for the solid phases. Very good agreement with the Monte Carlo simulations of Meijer and Frenkel [J. Chem. Phys. 94, 2269 (1991)] is found for both the fluid and the (fcc-bcc) solid phases. The location of the two-phase coexistences, however, is shown to involve such small free-energy and density changes that no definite statements about the phase diagram are possible within the present accuracy.
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En línea:
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https://eprints.ucm.es/id/eprint/23948/1/F-Tejero27.pdf
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